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dodecafluoroheptyl
methacrylate
Actyflon-G04
Molecular Formula:C11H8O2F12
Molecular weight:400
CAS:
Physical and Chemical properties
Item |
Requirement |
Appearance |
Colorless Clear Liquid |
Density,g/ml,25℃ |
1.589 |
Refractive
index(ηD25) |
1.5492 |
Boiling
point,℃ |
160-170 |
Flash point,closed
cup,℃
|
57 |
Vapour pressure,KPa,℃
|
13 |
| Solubility,wt%,20℃water |
Not soluble
in water,almost soluble in all organic solvent |
Quality standards
Item |
Requirement |
Purity,≥,% |
96 |
moisture,≤,% |
0.5 |
chroma(APHA),≤ |
50 |
Acidity(about
methacrylic acid),≤,% |
0.5 |
Properties
The Actyflon-G04 is a polyfluorine-containing
monomer of polymers which may reinforce to resin’s performance.
The polymers of this G04-containing has excellent heat and chemical
resistance , stain resistance , low refractive index, non-cohesiveness,
water and oil repellency, electric insulating properties.and etc
,because it contains plentiful fluorine in its side chain, the
weight ratio of fluorine in its molecular weight is 57% and atom
ratio in its molecular is 40%. The tranquilization is better than
other monomers. The fluorine atom is very compact. In addition,
the distance of the C-F bond is short and the bonding energy is
higher than that of other bonds. This leads to a decrease in the
cohesive energy between molecules and lowers the surface free
energy of the polymer, thereby making the polymer less wettable
and adhesive. G04 can easily copolymerize with other acrylate-type
monomers, also can polymerize with polymers that have a reactive
functional group in their side chain such as (meth)acrylic acid,
hydroxyalkyl acrylate and hydroxyalkyl acryl amide.
Apply
the classification the introduction
Solvent-Type
Thermoplastic Paint
As
Actyflon-G04 can easily copolymerize with other acrylate-type
monomers, it is most suitable for formulating coatings. It is
known that the chemical resistance water and oil repellency and
weatherability of paint can be increased by copolymerizing Actyflon-G04
with acrylic monomer. the paint film also had excellent impact
resistance and adhesive properties when it cured in the room temperature.
Thermosetting
Paint
Actyflon-G04 can polymerize with polymers that have a reactive
functional group in their side chain such as (meth)acrylic acid,
hydroxyalkyl acrylate and hydroxyalkyl acryl amide. Its use in
thermosetting paint has been reported. And can cured in the room
temperature in the present curing agent. Actyflon-G04 can be decrease
in the gloss of the hardened paint film, and a chalking phenomenon
or cracking can take place, these defects are caused by hydrolysis
with moisture. Therefore, the problems such as durability and
weatherability and stain resistance are thought to be solved by
the copolymerization of Actyflon-G04 with others monomer.
Emulsion-Type Paint
The expectation of the development of emulsion-type paint containing
fluorine has been high from the viewpoint of environmental problems.
Actyflon-G04 has properties close to those of ordinary acrylic
monomers, although it is a fluorine-containing monomer; therefore
it does not affect the mechanical and chemical stability of the
latex. Instead, due to the surface-active effect by fluorine,
this monomer stabilizes the emulsion in the polymerization process,
making it possible to carry out the polymerization without an
emulsifying agent. To improve the mechanical and chemical stability
of the resulting latex, it was necessary to consider using graft
polymerization using a hydrophilic monomer. On the other hand,
in the case of ordinary acrylic emulsion type paint, it is necessary
to add an emulsifying agent in the polymerization.
UV-Curing Type Paint
A UV- or EB-curable paint in which no solvent or water was used
has been developed because of pollution/environmental concerns.
Like the case of other monomers, it is difficult to polymerize
Actyflon-G04 by the irradiation of light. It is most appropriate
to copolymerize it with some photo polymerizing monomer, and use
the resulting copolymer as a photo cross linking substance. The
resulting copolymer is UV cured, and the coating is hydrophobic.
Other Application Fields of Actyflon-G04
The possible use of Actyflon-G04 as a component for various special
paints is under study. this compound was used for the protective
coating for airplanes due to its high chemical resistance. Actyflon-G04
can used as a glazed coating for paper. The glazing process for
paper is necessary to provide the gloss to printed paper and protect
its surface. and has excellent abrasion resistance and adhesive
properties.
Package
and storage
1)
The product package ,the specification separately is 25kg/pail,0.5kg/buttle.
2) Take away lightly and put down gently,keep the package clean,avoid
high heat or frost.
3) Avoid the direct sunshine and rain,avoid being stroke and pressed.
Transport accorting to the normal dangerous goods.
4) Store in a cool,dry,well-ventilated,light-avoided area away
from heat,flames.
5) Storage temperature is 5℃-35℃,storage life is 12 months.
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